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Home > Science & Nature > Chemistry > Chemistry - Industrial & Technical > Materials Science of Membranes for Gas and Vapor Separation:
Materials Science of Membranes for Gas and Vapor Separation:
 
 
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Materials Science of Membranes for Gas and Vapor Separation:
"Materials Science of Membranes for Gas and Vapor Separation is a one-stop reference for the latest advances in membrane-based separation and technology. Put together by an international team of contributors and academia, the book focuses on the advances in both theoretical and experimental materials science and engineering, as well as progress in membrane technology. Special attention is given to comparing polymer and inorganic/organic separation and other emerging applications such as sensors.

This book aims to give a balanced treatment of the subject area, allowing the reader an excellent overall perspective of new theoretical results that can be applied to advanced materials, as well as the separation of polymers. The contributions will provide a compact source of relevant and timely information and will be of interest to government, industrial and academic polymer chemists, chemical engineers and materials scientists, as well as an ideal introduction to students. "



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Title of ebook: Materials Science of Membranes for Gas and Vapor Separation:
ISBN: 9780470029046
parent-ISBN: 9780470853450
Publisher: John Wiley & Sons, Ltd.
Internet download file size: 7422 kb
Published: 05-2006
Released online for download: 05-12-2006
Editor: Freeman, Benny
Editor: Yampolskii, Yuri
Editor: Pinnau, Ingo
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Chapter One

Transport of Gases and Vapors in Glassy and Rubbery Polymers

Scott Matteucci, Yuri Yampolskii, Benny D. Freeman and Ingo Pinnau

1.1 Background and Phenomenology

Transport in non-porous polymeric membranes is based on the so-called 'solution-diffusion' concept. This model, formulated in the 19th century, is grounded in the works of J. K. Mitchell, T. Graham and S. von Wroblewski, who demonstrated that the presence of microscopic open pores or capillaries was not a prerequisite for mass transfer through polymeric films (or septa as they were referred to), such as natural rubber. First, Graham in 1829, and then Mitchell in 1831, noted that gases were capable of permeating through non-porous rubber films and that this process was related to gas dissolution and diffusion in the polymeric materials. The currently accepted interpretation of such experiments was given several decades later by Graham (this and other articles from the early history of membrane science have been reproduced, in part, in a special ... read full excerpt from Materials Science of Membranes for Gas and Vapor Separation: ebook



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