Advances in Photochemistry
Chapter One
SUPRAMOLECULARLY
ORGANIZED LUMINESCENT
DYE MOLECULES IN THE
CHANNELS OF ZEOLITE L
Gion Calzaferri, Huub Maas, Marc Pauchard, Michel Pfenniger,
Silke Megelski, and Andri Devaux
Department of Chemistry and Biochemistry, University of Bern,
CH-3000 Bern 9, Switzerland
CONTENTS
I. Introduction
II. The System
A. Geometrical Constraints
B. Inner- and Outer-Surface of the Zeolite Nanocrystals
C. The Dyes
D. Three-Dye Antenna
E. The Stopcock Principle
III. Transfer of Electronic Excitation Energy
A. Radiationless Energy Transfer
B. Fvrster Energy Transfer in Dye Loaded Zeolite L
C. Spectral Overlap
IV. Elegant Experiments for Visual Proof of Energy Transfer
and Migration
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