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Home > Science & Nature > Chemistry > Chemistry - Organic > Topics in Stereochemistry-eBook
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Topics in Stereochemistry
"Topics in Stereochemistry, previously edited by ""the father of stereochemistry"" Ernest L. Eliel, is a longstanding, successful series covering the most important advances in the field. The much-anticipated Volume 25 includes chapters on the following topics:
  • Stereochemistry of Molecules in Inclusion Crystals
  • Torsional Motion of Stilbene-type Molecules in Crystals
  • Supramolecular Networks of Porphyrins
  • Homo- and Heterochirality in Crystals
  • Supramolecular Synthesis of 1D Chains and 2D Layers in Hydrogen Bond Networks of Ureas and 2-D Pyrimidinones
  • Chiral Auxiliaries Powerful for Both Enantioresolution and Determination of Absolutely Stereochemistry by X-Ray Crystallograph
  • Engineering Stereospecific Reactoins in Crystals: Synthesis of Compounds with Adjacent Stereogenic Quaternary Centers by Photodecarbonylation of Crystalline Ketones
  • The CH/ Hydrogen Bond: An Important Molecular Force in Controlling the Crystal Conformation of Organic Compounds and Three-Dimensional Structure of Biopolymers
  • Stereoselective Thermal Solid-State Reactions
  • Crystal Structures and Functionalities of Platinum (II) Complexes Controlled by Various Intermolecular Interactions
"
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Title of ebook: Topics in Stereochemistry
ISBN: 9780471785088
Publisher: Wiley-Interscience
Internet download file size: 7824 kb
Pages: 403
Released online for download: 04-27-2006
Author of eBook: Denmark, Scott E.
Author of eBook: Siegel, Jay



Chapter One

Stereochemistry of Molecules in Inclusion Crystals

FUMIO TODA

Department of Chemistry, Okayama University of Science, Ridia-cho1-1, Okayama 700-0005, Japan

I. Introduction

II. Separation of Stereoisomers

A. Separation of a Component of an Equilibrium Mixture

B. Separation of Conformational Isomers of [alpha]- and ß-Ionones, Acrylic Acid, and 1,2-Dichloroethane

C. Separation of Conformational Isomers of Cyclohexane Derivatives

III. Chiral Conformers of Achiral Molecules in Their Own Crystals

IV. Control of Stereochemistry of Molecules in Crystals for Selective Reactions

Acknowledgments

References

I. INTRODUCTION

A stereoisomer can be studied precisely if it is isolated in a pure st ... read full excerpt from Topics in Stereochemistry ebook



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