Chapter One
Stereochemistry of Molecules in Inclusion Crystals
FUMIO TODA
Department of Chemistry, Okayama University of Science,
Ridia-cho1-1, Okayama 700-0005, Japan
I. Introduction
II. Separation of Stereoisomers
A. Separation of a Component of an Equilibrium Mixture
B. Separation of Conformational Isomers of [alpha]- and ß-Ionones, Acrylic Acid, and
1,2-Dichloroethane
C. Separation of Conformational Isomers of Cyclohexane Derivatives
III. Chiral Conformers of Achiral Molecules in Their Own Crystals
IV. Control of Stereochemistry of Molecules in Crystals for Selective Reactions
Acknowledgments
References
I. INTRODUCTION
A stereoisomer can be studied precisely if it is isolated in a pure state from a
mixture of stereoisomers. When the stereoisomer is a component of an equilibrium
mixture, its isolation in a pure state is more difficult. The usual method is
X-ray crystallographic a ... read full excerpt from Topics in Stereochemistry ebook
