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Quinone Methides (Wiley Series of Reactive Intermediates in Chemistry and Biology #4)
By: S. E. RokitaeBook Publisher: John Wiley & Sons
Imprint: Wiley-Interscience
Format: Adobe Encrypted (DRM)
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Multidisciplinary perspectives and approaches to quinone methides research
The Wiley Series on Reactive Intermediates in Chemistry and Biology investigates reactive intermediates from the broadest possible range of disciplines. The contributions in each volume offer readers fresh insights into the latest findings, emerging applications, and ongoing research in the field from a diverse perspective.
This inaugural volume in the series, Quinone Methides, represents the first book devoted to this fascinating and useful intermediate. The authors of this work reflect the many disciplines and approaches to quinone methides research. The volume therefore covers a broad range of topics, including theoretical treatments, generation and detection of intermediates, characterization and applications in chemistry and biochemistry, and biological reactivity. Among the chapters are:
Photochemical generation and characterization of quinone methides
Quinone methide stabilization by metal complexation
Self-immolative dendrimers based on quinone methides
Characterization of quinone methides by spectral global fitting and 13C labeling
Formation and reactions of xenobiotic quinone methides in biology
Quinone methides in lignification
With this collection of topics, readers already familiar with quinone methides have the opportunity to advance their own research by discovering new inspiration and opportunities in allied areas. Moreover, the range of topics and perspectives covered make this volume accessible to readers with a broad range of interests, including organic and physical chemistry, biochemistry, biotechnology, and pharmaceutics.
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| Title of eBook: Quinone Methides (Wiley Series of Reactive Intermediates in Chemistry and Biology #4) | |
| Release Date: 02-17-2009 | |
| Publisher: Wiley-Interscience |
This eBook download is available in the following formats:
| Parent title | Quinone Methides (Wiley Series of... |
|---|---|
| Encrypted (DRM) | Yes |
| SKU | 9780470452875 |
| File size | 10192 |
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| Note | Excellent navigation features are available via Adobe such as bookmarks and a quick access table of contents. Text search is easily accessible. An Adobe DRM-protected file is different than a pdf file in that it uses Adobe DRM (Digital Rights Management) technology, which authors and publishers use to protect their content from illegal online distribution and to set certain privileges such as restrictions on copying and printing. |
Quinone Methides (Wiley Series of Reactive Intermediates in Chemistry and Biology #4)
Chapter One
PHOTOCHEMICAL GENERATION AND CHARACTERIZATION OF QUINONE METHIDES
Matthew Lukeman Department of Chemistry, Acadia University, Wolfville, Nova Scotia, Canada B4P 2R6
1.1 INTRODUCTION
Quinone methides (QMs) are reactive intermediates that are commonly encountered in many areas of chemistry and biology. Quinone methides contain a cyclohexadiene core with a carbonyl and a methylene unit attached and are related to quinones, which have two carbonyl groups, and quinone dimethides, which have two methylene groups. Quinone methides are highly polar and are much more reactive than their relatives. Ortho (1) and para (2) quinone methides are the most commonly encountered isomers, although meta-quinone methides (3), which are non-Kekul
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