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van der Heide, Paul X-ray Photoelectron Spectroscopy eBook

X-ray Photoelectron Spectroscopy

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eBook Publisher: John Wiley & Sons
Imprint: Wiley

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This book introduces readers interested in the field of X-ray Photoelectron Spectroscopy (XPS) to the practical concepts in this field. The book first introduces the reader to the language and concepts used in this field and then demonstrates how these concepts are applied. Including how the spectra are produced, factors that can influence the spectra (all initial and final state effects are discussed), how to derive speciation, volume analysed and how one controls this (includes depth profiling), and quantification along with background substraction and curve fitting methodologies.

 

This is presented in a concise yet comprehensive manner and each section is prepared such that they can be read independently of each other, and all equations are presented using the most commonly used units. Greater emphasis has been placed on spectral understanding/interpretation. For completeness sake, a description of commonly used instrumentation is also presented. Finally, some complementary surface analytical techniques and associated concepts are reviewed for comparative purposes in stand-alone appendix sections.

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Title of eBook: X-ray Photoelectron Spectroscopy
Release Date: 11-01-2011
Publisher: Wiley

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Parent title X-ray Photoelectron Spectroscopy
Encrypted (DRM) Yes
SKU 9781118162927
File size 19079
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X-ray Photoelectron Spectroscopy


Chapter One

INTRODUCTION

1.1 SURFACE ANALYSIS

We interact with our surroundings through our five senses: taste, touch, smell, hearing, and sight. The first three require signals to be transferred through some form of interface (our skin, taste buds, and/or smell receptors). An interface represents two distinct forms of matter that are in direct contact with each other. These may also be in the same or different phases (gas, liquid, or solid). How these distinct forms of matter interact depends on the physical properties of the layers in contact.

The physical properties of matter are defined in one form or another by the elements present (the types of atoms) and how these elements bond to each other (these are covered further in Section 2.1). The latter is referred to as speciation.

An example of speciation is aluminum (spelt aluminium outside the United States) present in the metal form versus aluminum present in the oxide form (Al2O3). In these cases, aluminum exists in two different oxidation states (Al0 vs. Al3+) with highly diverse properties. As an example, the former can be highly explosive when the powder form is dispersed in an oxidizing environment (this acted as a booster rocket propellant for the space shuttle when mixed with ammonium perchlorate), while the latter is extremely inert (this is the primary form aluminum exists within the earth's crust).

Aluminum foil (the common household product) is primarily metallic. This, however, is completely inert to the environment (air under standard temperature and pressure) since it is covered by a thin oxide layer that naturally reforms when compromised

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